Substances

Toluene

Also called methylbenzene, toluol.

A highly flammable solvent found in paints, adhesives and thinners. Suspected of harming the unborn child, and can be absorbed through the skin. Prolonged exposure damages the nervous system.

Last reviewed 8 September 2026

Hazard data from the HSE GB MCL, the ECHA C&L Inventory and HSE EH40, checked 8 September 2026. Classification checked automatically against the HSE GB mandatory classification list (version 8) and the ECHA C&L inventory on 9 September 2026. Confirm the concentration and form against the supplier data sheet for the product you use.

Identification

CAS number108-88-3
EC number203-625-9
Physical formliquid
Signal wordDANGER
PictogramsGHS02 Flammable; GHS07 Harmful or irritant; GHS08 Serious health hazard
Routes of exposureinhalation, skin, ingestion

Hazard classification

Harmonised classification from the GB mandatory classification list (index 601-021-00-3).

  • Flammable liquid, category 2
  • Reproductive toxicity, category 2
  • Aspiration hazard, category 1
  • Skin irritation, category 2
  • Specific target organ toxicity, single exposure, category 3
  • Specific target organ toxicity, repeated exposure, category 2

Hazard statements

  • H225 Highly flammable liquid and vapour.
  • H361d Suspected of damaging the unborn child.
  • H304 May be fatal if swallowed and enters airways.
  • H315 Causes skin irritation.
  • H336 May cause drowsiness or dizziness.
  • H373 May cause damage to organs through prolonged or repeated exposure.

Workplace exposure limit

Reference periodppmmg/m³
Long term (8 hour TWA)50191
Short term (15 minute)100384

Carries a skin notation (Sk). The substance can be absorbed through the skin, so skin exposure counts towards the total dose.

Common uses

  • Paint and adhesive solvent
  • Thinners
  • Printing

First aid

Inhaled: fresh air. Skin: wash with soap and water. Swallowed: do not induce vomiting, call 999.

In an emergency call 999. For advice call NHS 111. Always follow section 4 of the safety data sheet for the product you have.

Storage

Flammables cabinet, closed container, away from ignition sources.

Sources

We do not host or copy manufacturer safety data sheets. Ask your supplier for the current sheet for the product you use.